Journal article

Full citation: 

Skip Nav Destination RESEARCH ARTICLE| MARCH 22, 2021 Anaerobic oxidation of methane by Mn oxides in sulfate-poor environments Chunfang Cai; Kaikai Li; Dawei Liu; Cedric M. John; Daowei Wang; Bin Fu; Mojtaba Fakhraee; Hong He; Lianjun Feng; Lei Jiang Geology (2021) 49 (7): 761–766. Article history Standard View PDF LinkPDF Cite Share Icon Share Tools Icon Tools Abstract Strongly 13C-depleted authigenic carbonates (e.g., δ13CVPDB <−30‰; VPDB—Vienna Peedee belemnite) in nature are generally believed to form by sulfate-dependent anaerobic oxidation of methane (AOM). However, we demonstrate using geochemical data and thermodynamic calculation that such calcites are most likely derived from biogenic oxidation of methane in sulfate-poor, nonmarine environments during early diagenesis, as observed in the Triassic sandy conglomerates from the Junggar Basin, northwestern China. This process operated through preferential oxidation of 13C-depleted methane by Mn oxides in closed conditions, producing calcites with higher Mn contents and δ13C values in association with more 13C-enriched residual methane as a result of kinetic isotope fractionation. Thus, the Mn-rich and 13C-depleted carbonates are proposed as tracers of Mn-dependent AOM, which should have served as an important sink of greenhouse methane in low-sulfate early Earth's oceans.

Publication date: 
Monday, March 22, 2021